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Revista de la Sociedad Química del Perú

Print version ISSN 1810-634X


BURGER, Klaus; HOß, Eva  and  HENNIG, Lothar. Domino reactions with 5-azido- and 5-amino-4- trifluoromethyl-1,3-azoles.. Rev. Soc. Quím. Perú [online]. 2005, vol.71, n.1, pp.12-16. ISSN 1810-634X.

Compounds with substructures like CF 3 -C=C-NH-R are remarkable reactive towards primary amines. They behave like "ortho-fluorides" and are readily susceptible to elimination / addition sequences which can be linked together and performed as domino reactions.

Keywords : 5-Fluoro-4-trifluoromethyl-1,3-azoles; 5-azido-4-trifluoromethyl-1,3-azoles; 5-amino-4-trifluoromethyl-1,3-azoles; domino reaction; [1.4] HF-elimination; Michael addition.

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